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Material
safety data sheet (MSDS)
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1. Chemical
product and company identification
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| Trade
name |
: |
Oleic
- 99 |
| Manufacture's
name address |
: |
Godrej
Industries Limited, Eastern Express Highway, Vikhroli (east), Mumbai.
India.
Pin - 400 079. |
| Telephone |
: |
91-22-518
80-10 / 20 / 30 |
| Fax |
: |
91-22-518
80-69 / 96 / 81 |
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2. Composition
/ ingredients
|
| Chemical
composition |
: |
Oleic
acid 99% |
| Average
molecular weight |
: |
282.5 |
Chemical
identity
CH3 (CH2)7 CH = CH (CH2)7
COOH |
: |
Synonym:
Octadecanoic acid
|
CAS
number
112-80-1 |
| 3.
Hazard identification (reference: 4) |
| Health
rating |
: |
Slight |
| Flammability
rating |
: |
Slight |
| Reactivity
rating |
: |
Slight |
| Contact
rating |
: |
Slight |
| Storage |
: |
General |
| 4.
First-aid measures (reference: 4) |
| Ingestion |
: |
Drink
plenty of water. |
| Skin |
: |
Remove
contaminated clothing and wash exposed area with plenty of water.
Then wash again with soap and water. |
| Eye |
: |
Wash
eyes with plenty of water. |
| Inhalation |
: |
Take
affected person into the open air and allow him to rest. |
| *In
all of the above cases, get a doctor to check the affected person. |
| 5.
Fire hazard and fire-fighting measures (reference: 1, 4) |
| Flammability |
: |
Flammable
and combustible in contact with heat or fire. |
| Means
of extinguishing |
: |
Use
water spray, carbon dioxide, dry chemical, or alcohol foam. Use water
to keep fire-exposed container cool. |
| Flash
point |
: |
189°
C |
| Auto
ignition |
: |
363°
C |
| Hazardous
combustion product |
: |
Organic
cracked hydrocarbons and carbon oxides |
| 6.
Accidental release measures (reference: 4) |
| Personal
protection |
: |
Use
complete protective gear as prescribed in section 8. There's a high
risk of slipping since the product is a liquid. |
| Leak-and-spill
procedures |
: |
Remove
sources of ignition, ventilate area, sweep up the liquid in dry sand,
and shovel it into a closed container. Collect spillages into sumps
/ traps to minimise contamination of drains, surface and ground water. |
| 7.
Handling and storage measures (reference: 4, 5) |
| Handling
containers |
: |
Use
full protective gear. Protect containers against physical damage /
direct sunlight / water. |
| Storage
conditions of containers |
: |
Use
leak-proof and compatible drums. Store in dry and well-ventilated
locations, at ambient temperature away from direct sunlight. |
| 8.
Exposure controls and personal protection measures (reference: 4,
5) |
| Engineering
controls |
|
Use adequate
ventilation to keep airborne concentrations low. Avoid inhalation
of heated vapours.
TLV: None listed.
PEL: None listed.
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| Personal
protection |
| Skin |
: |
Rubber
gloves |
| Respiration |
: |
Air
respirator |
| Eyes |
: |
Goggles |
| Feet |
: |
Safety
shoes |
| Body |
: |
Lab
coat |
| Hygiene
precautions |
: |
Remove
contaminated clothing and wash hands between breaks and at the end
of duty hours. |
| 9.
Physical and chemical properties (reference: 1, 4, 5) |
| Physical
state |
: |
Liquid
above 20° C |
| Odour
and appearance |
: |
Pale
yellow liquid with slight odour |
| Specific
gravity |
: |
0.895
at 17.7° C |
| Boiling
point |
: |
264°
C at 50mm |
| Melting
point |
: |
13°
C to 20° C |
| Vapour
pressure |
: |
1mm
at 176.5° C |
| Solubility
in water (20° C) |
: |
Insoluble |
| 10.
Reactivity data (reference: 4, 5) |
| Chemical
stability |
: |
Product
is stable under the prescribed storage conditions. |
| Incompatibility
with substances |
: |
Perchloric
acid |
| Reactivity
/ conditions |
: |
Peroxidised
acid with aluminium |
| Hazardous
decomposition |
: |
Acrid
smoke and irritating fumes when heated above its boiling point. |
| Hazardous
polymerisation products |
: |
None |
| 11.
Toxicological properties (reference: 2, 3, 4, 5) |
| Toxicity |
: |
Non-toxic |
| Skin
contact |
: |
Slight
erythema |
| Inhalation
|
: |
Slight |
| Skin
absorption |
: |
Slight |
| Eye
contact |
: |
Slight
irritation |
| Ingestion |
: |
rat
LD 50 > 21.5 ml/kg |
| Effect
of acute and chronic exposure to material |
: |
The
extensive use of oleic acid in industry has not been accompanied by
any reports of injury. |
| Irritancy
of material |
: |
Slight |
| Carcinogenicity,
reproductive effects, terratogenicity, mutagenicity |
: |
None
reported |
| 12.
Ecological information (reference: 4, 5) |
The
product should not get into any kind of water without treatment. Dissolved
in water, the material is easily biodegradeable (90 per cent) and
will not cause any disturbance in waste water treatment plants. Due
to its insolubility in water, larger amounts need to be eliminated
by separators such as those typically used for fats and oils.
Aquatic ecotoxicity
Fish LC50 ( 96 hrs ) > 205 mg/L |
| 13.
Waste disposal (reference: 4, 5) |
| Leak-and-spill
procedures |
: |
Sweep
up the liquid in dry sand and shovel into a closed container. |
| Disposal |
: |
Stored
waste / recovered material used for recycling along with crude oils. |
| 14.
Transport recommendation (reference: 4, 5) |
| No
special conditions since it is not a regulated product. However, one
should observe the usual precautionary measures for transporting chemicals. |
| 15.
Regulatory requirements (reference: 4, 5) |
|
According to
available data, the product is not regulated. However, one should
observe prescribed federal, state and local measures while dealing
with chemicals.
Hazard identification: irritant
Risk phrases: R 36, 38
Safety phrases: S 2, 24, 25
The above mentioned classification is valid for industrial users
of this product.
Listed on EINECS (EU), TSCA (USA), DSL (Canada), AICS (Australia)
and MITI (Japan).
EINECS No: Oleic acid 204-007-1
Not listed as a carcinogen by NTP, IARC or OSHA.
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| 16.
Other information |
Sources
of information:
1. Fatty acids — Klare Markley (1960)
2. Palm oil developments No 28 — pages 22 to 49 (March 1998)
3. JAOCS 56 — page 760A - 767A (1979)
4. ICN Biochemicals — MSDS of oleic acid (31-12-1998)
5. Dr Frische, GMBH — MSDS of oleic acid 90% (24-01-01) |
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Disclaimer
The
information presented here is believed to be accurate. It pertains
only to the product when stored in a sealed condition, as prescribed
here. The information is given in good faith, but no warranty, express
or implied, is made. Users should make their own investigations,
for their specific applications and processes, to determine the
suitability of the safety information mentioned here. Godrej Industries
Limited will in no way be liable for any claims, losses and / or
damages of any third party, or for lost profits, or any special,
indirect, incidental, consequential or exemplary damages, howsoever
arising, from the use of this product.
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